Product ID:VR-3-VINYL RESIN-WHITE, 112-011
MSDS Date:06/27/1988
FSC:8010
NIIN:00N020611
MSDS Number: BLMCW

D J SIMPSON CO

111 SOUTH MAPLE AVE SOUTH
SAN FRANCISCO, CA 94080
US

Emergency Phone: 415-873-5990

Info Phone: 415-873-5990

Cage: HO834

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

CONTAINERS MAY EXPLODE DUE TO RESIDUE.

RTECS: 9999999ZZ

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 10 - 15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 5 - 10%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 30 - 48%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NTP/IARC CONFRMED

RTECS: 9999999ZZ

IRRITANT AND ANIMAL CARCINOGEN.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:ANESTHETIC.
DIZZ/NAUSEA/HDCH/IRRIT OF RESP TRACT, UNCON, COMA & EVEN ASPHY AT
HIGH CONC. IT HAS BEEN FOUND THAT TOLUENE CNTNS A COMPONENT WHICH
CAN CAUSE IRREVERSIBLE CHANGES IN THE DNA OF THE C ELL.
SKIN:IRRIT/DRYING/CRACKING. EYE: IRRIT/EYE BURN. SKIN ABSORP:
SEVERE IRRIT/BURNING SENS/CRACKING,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DEFAT & DERM MAY OCCUR ON PRLNG EXPOS.
INGEST: DIZZ/NAUSEA. NOT EXPECTED TO HAVE ACUTE SYSTEM TOX BY
INGEST. NOTE TO MD: INGEST OF PROD/SUBSEQUENT VOMIT CAN RESULT IN
ASPIR OF LIGHT HYDROCARB ON LIQ INTO LUNGS WHICH CAN CAUSE
(SUPPDATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING HEART, LUNG, KIDNEY,
LIVER AND SKIN DISORDERS.

First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BRTHG. GIVE O*2 IF
NEEDED. SEEK MED HELP IMMED. EYE: FLUSH WITH LRG AMTS OF WATER FOR
AT LEAST 15 MIN WITH EYELIDS OPEN. SEE A PHYSICIAN IMMED. SKIN:
WASH WITH SOA P AND WATER. REMOVE CONTAM CLTHG. INGEST: DO NOT
INDUCE VOMTING. DRINK ONE OR TWO GLASSES OF WATER TO DILUTE. SEEK
MEDICAL HELP IMMED. KEEP PATEINT QUIET, WARM AND COMFORTABLE.

Flash Point Method:TCC
Flash Point:16.0F,-8.9C
Lower Limits:1.2 %
Upper Limits:7 %
Extinguishing Media:FOAM, CO2, DRY CHEMICAL OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. USE H2O TO COOL FIRE EXPOS CNTNRS. AVOID SPREADING FIRE W/
COOLING H2O. FOG NOZ FOR H2O. (SUPP DATA)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLO WHEN EXPOS TO
EXTREME HEAT. VAP MAY TRAVEL TO SOURCES OF IGNIT & CAUSE A FLASH
FIRE. ISOLATE FROM ALL SOURCES OF HEAT. EMPTY (INGRED 7)

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CONTAIN AND REMOVE WITH INERT ABSORBANT AND NON-SPARKING
TOOLS. WEAR PROTECTIVE EQUIPMENT DURING CLEANUP. CONTAIN LIQUID TO
PREVENT CONTAMINATION OF SOI L & GROUND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CNTNR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES OF IGNIT. CNTNRS MUST
BE GROUNDED &/OR BONDED DURING LIQ TRANSFER.
Other Precautions:HNDL WHERE VENT IS ADEQ & AWAY FROM SOURCES OF IGNIT
EMPTIED CNTNR MAY STILL CNTN HAZ MATL HENCE IT IS ADVISED TO
OBSERVE THIS MSDS WHEN HNDLG THEM. AVOID PRLNG BRTHG OF VAPS, SKIN
OR EYE CNTCT. IN CA SE OF CNTCT, WASH THORO WITH (SUPP DATA)

Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER
RESPIRATOR.
Ventilation:REQUIRED, 200 CFM MINIMUM.
Protective Gloves:CHEMICALLY RESISTANT PLASTIC OR RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & SAFETY SHOWERS IN WORK AREA
RECOMMENDED. USE PROTECTIVE HAND CREAMS TO PREVENT DEFAT OF SKIN
UPON EXPOSURE.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLTHG BEFORE HANDLING FOOD OR SMOKING. DAILY SHOWERS RECOMMENDED.
Supplemental Safety and Health
EFTS OF OVEREXP:FATAL CHEM PNEUMONITIS. RPTD & PRLNG OCCUP OVEREXP TO
SOLV IN PROD MAY LEAD TO PERMNENT BRAIN/NERV SYS DAMAGE. (ASLO
KNOWN AS PAINTER'S/SOLV SYNDROME). FIRE FIGHT PROC: FIGHT AS VOLATI
LE LIQUID FIRE. OTHER PREC: SOAP & H*2O. THIS MATL CNTNS < 1 %
PHOSPHORIC ACID & < 0.1 % BY WT VINYL CHLORIDE (ING 5)

HCC:F3
Boiling Pt:B.P. Text:> 174F,79C
Vapor Pres:HVR/AIR
Spec Gravity:1.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:VISCOUS LIQUID WITH DISTINCT SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS, ACIDS AND BASES.
Stability Condition to Avoid:AVOID PROLONGED BREATHING OF VAPORS, SKIN
OR EYE CONTACT. STORE AWAY FROM HEAT, ELECTRICAL EQUIP, SPARKS OR
OPEN FLAME.
Hazardous Decomposition Products:USUAL PRODUCTS OF COMBUSTION; CARBON
DIOXIDE, CARBON MONOXIDE, OTHER OXIDES, SMOKE FUMES, ETC.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

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particular situation.